Environmental Engineering,
B. Momenpoor; F. Danafar; F. Bakhtiari; A. Namjoo
Abstract
The properties of the Nanoclay-corn starch film were studied in the presence of Nanostarch. Nanostarch was synthesized through nanoprecipitation and characterized using the Particle Size Distribution Analysis, Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction Analysis (XRD), and ...
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The properties of the Nanoclay-corn starch film were studied in the presence of Nanostarch. Nanostarch was synthesized through nanoprecipitation and characterized using the Particle Size Distribution Analysis, Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction Analysis (XRD), and Fourier Transform Infrared Analysis (FTIR). The XRD analysis of nanostarch particles revealed a distinctive V-type diffraction peak, with particle diameters ranging from 25 to 100 nm. The impact of introducing nanostarch into the starch-nanoclay film was investigated in terms of the thickness, transparency, morphology, wettability, and mechanical properties of the nanocomposite film. The results indicated that adding nanostarch particles improved the optical transparency of the film along with its hydrophobicity and flexibility. The film having a weight ratio of 0.769 (nanoclay to nanostarch) showed the maximum hydrophobicity (107.85°), and elongation at break (58.6%). This suggests that the appropriate incorporation of nanostarch can enhance the film's flexibility. The maximum tensile strength (5.88 MPa) was obtained for the film with a weight ratio of 1 (nanoclay to nanostarch).
Energy
H. Amiri; A. Babapoor; M. Fallahi-Samberan; N. Azimi; A. Hadidi
Abstract
Current research has simulated polymer oxide/metal oxide nanofibers (nanocomposites) through the COMSOL Multiphysics software. The oil was placed inside a cylindrical tank covered with a thin layer of phase change material nanocomposites. A combination of polyethylene glycol (PEG) as a the phase change ...
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Current research has simulated polymer oxide/metal oxide nanofibers (nanocomposites) through the COMSOL Multiphysics software. The oil was placed inside a cylindrical tank covered with a thin layer of phase change material nanocomposites. A combination of polyethylene glycol (PEG) as a the phase change material (PCM) and polyamide 6 (PA6) as a support matrix for nanofibers were used. The effect of some parameters such as the type of metal oxide nanoparticles (Al2O3, Fe2O3, TiO2, and CuO), the ratio of metal oxide to polymer (2% and 8% by weight), and time (600 and 4800 s) on some thermophysical properties such as changes in temperature, density and thermal conductivity were investigated. The simulation results showed that the most suitable system for thermal management is related to the presence of nanoparticles and PCM with the highest weight percentage. It was also found that the use of the nanofibers of phase change materials is very effective in improving thermal management and temperature control. As a result, they can be used as suitable materials for storing and transferring energy. The addition of 8% nanoparticles led to a 22.5% increase in thermal conductivity. Also, by providing the same initial and boundary conditions for all cases, the amount of melting in the presence of nanoparticles with a high percentage (8%) was higher than the with a low percentage (2%). As a result, the addition of nanoparticles to increase the melting rate can be very useful for various heat management purposes such as energy storage.
Process Control and Engineering, Process Safety, HSE
Sh. Mehmandoust; M. R. Moghbeli1*; M. Dadban; H. Karimian
Volume 12, Issue 3 , July 2015, , Pages 41-54
Abstract
"> Sodium montmorillonite (Na-MMT) was organically modified using 11- aminoundecanoic acid (AUA) and methacryloxyethyltrimethylammonium chloride (MAETAC) via cation exchange reaction. The effect of the modifier type and concentration on the structure and surface properties of the organically modified ...
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"> Sodium montmorillonite (Na-MMT) was organically modified using 11- aminoundecanoic acid (AUA) and methacryloxyethyltrimethylammonium chloride (MAETAC) via cation exchange reaction. The effect of the modifier type and concentration on the structure and surface properties of the organically modified montmorillonites (OMMTs) was investigated. According to the results, the basal spacing of organoclays was enlarged considerably with increasing the AUA concentration, while increasing the MAETAC concentration had no significant influence on OMMT’s gallery height. On the other hand, contact angle measurements revealed that increasing the modifiers concentration would increase the hydrophobicity of pristine montmorillonite. The FTIR spectra showed that the OMMTs interlayer environment changed from liquid-like to solid-like as the modifier concentration increased. A mean-field lattice-based model was applied to various polymer/OMMT systems to predict the affinity between the prepared OMMTs and some polymers with different hydrophobicity. The model results showed that high polar and hydrophilic polymers, such as poly(ethylene oxide), exhibit more negative free energy change and stronger interaction with the OMMTs and, consequently, higher potential for preparation of composites with desirable nanostructure and mechanical properties.