Full article
Mona Morovat; Omid Bakhtiari
Abstract
Ability and compatibility of the membrane processes for gas separation are evaluated by their membranes’ permeability and selectivity where both have been tried to enhance in promising membrane generation of mixed matrix membranes (MMMs). In the current study, two- and three-dimensional models ...
Read More
Ability and compatibility of the membrane processes for gas separation are evaluated by their membranes’ permeability and selectivity where both have been tried to enhance in promising membrane generation of mixed matrix membranes (MMMs). In the current study, two- and three-dimensional models were constructed for MMMs, and the Fick's first law was solved numerically in them by using the Finite Element Method (FEM) and Computational Fluid Dynamic (CFD) tools. The effects of different MMMs structural parameters such as the volume fraction, size and mode of packing, i.e., regular or random, of the filler particles were investigated on the effective permeability of the pure gaseous penetrants through the MMMs. Furthermore, the interfacial equilibrium constant of the penetrants and their diffusivity ratios were also evaluated in view point of their impacts on the MMMs’ separation performance. Some well-known established models including Maxwell, Bruggeman, Lewis - Nielsen, Pal, and Chiew - Glandt were applied in the modeling. Deviation of the simulation results from the experimentally measured ones were low enough, however, at higher loadings of the filler particles the simulation deviation became greater. Simulated results through PSF - MCM-41 MMMs were compared with those of experimentally measured ones and AAREs of 31.0 (The lowest deviation), 42.7, and 41.0 % obtained for CO2, O2, and N2, respectively.
Full article
Process Control and Engineering, Process Safety, HSE
vida zaroushani; hedieh mirzakhani; farahnaz khajehnasiri
Abstract
Natural gas (NG) is one of the cleanest and safest sources of energy transmitted in a high pressure that must be reduced before entering City Gas Station (CGS). Identifying the effective parameters in creating the hazardous areas of CGS is essential to crisis and management. This study using PHAST version ...
Read More
Natural gas (NG) is one of the cleanest and safest sources of energy transmitted in a high pressure that must be reduced before entering City Gas Station (CGS). Identifying the effective parameters in creating the hazardous areas of CGS is essential to crisis and management. This study using PHAST version 7.11(created by DNV Company) conducted a consequence modelling in three scenarios at three CGS stations in Qazvin Province, by actual data including weather conditions, gas pressure and temperature. The main results for the modeling in all three scenarios were jet fire, flash fire, and explosion. Based on the modeling results, most flame length was obtained in Avaj station with 10 meters more than others. Most radiation levels were also in Avaj station in about 150 m downwind distance, which can be caused by the longer flame length in this station.The results showed that in fire jet modeling, an increase in air temperature can lead to an increase in gas pressure and temperature, which in this study increased the flame length of 2 to 3 meters. However, the flame length and the hazardous area was higher during the day and summer. The use of PHAST modeling software can provide useful information including high-risk operational area, hazard area, high-risk time period (day, night and season) for the management team to respond to emergency situations in process industries. In addition, it is necessary to consider the combination of different operating parameters such as gas pressure and gas temperature with different weather conditions.