Iranian Journal of Chemical Engineering (IJChE)

Abstract Modern steam turbines employ extended low-pressure blades, subjecting root connections to severe centrifugal and thermal loads. As a result of these loadings, various and severe dynamic stresses are formed in the structure. Understanding the distribution of these stresses and conducting studies on it will greatly help determine the lifespan of items and how to manage them. This study evaluates stress and strain distributions in Ti-6Al-4V turbine roots, specifically comparing BLISK and fir-tree designs under operational conditions. Using the nonlinear Finite Element Analysis (FEA) and Local Plastic Stress and Strain Analysis (LPSA), the peak von Mises stress was identified as 890.76 MPa for the BLISK and 390.82 MPa for fir-tree roots. Advanced damage frameworks, including the Modified Mohr-Coulomb and Lemaitre's CDM models, are discussed conceptually to identify critical stress triaxiality states, thereby establishing a reliable baseline for subsequent fracture analyses. The findings establish a reliable baseline for fatigue studies, identifying root-blade transition fillets as critical sites for low-cycle fatigue failure. Understanding the behavior of materials under fatigue loading can help in better determining the scope of application of the design and optimizing it.

Abstract In this novel study, various heat exchangers are compared to identify the most efficient one for heat transfer. This investigation involves shell and tube, double pipe, and plate heat exchangers, of which each is filled with different nanofluids. Following several hours of operation, output temperatures are recorded. The effects of nanofluids, containing aluminium oxide, magnesium oxide, and silicon oxide, at concentrations of 0.2%, 0.4%, and 0.6% are simulated. These simulated results are then compared with laboratory findings. Among the tested nanofluids, the most significant enhancement in the heat transfer coefficient is demonstrated by magnesium oxide, achieving a 40% improvement. Additionally, graphs illustrating the increase in the heat transfer coefficient and Nusselt number for Reynolds numbers of 900, 600, 300, and 1800 are obtained and compared. Finally, tables summarizing the tests performed on different heat exchangers using various nanofluids are presented. Using laboratory-obtained temperatures, several parameters are calculated, including the logarithmic mean temperature difference, heat loss from hot water, heat gain by cold water, overall heat transfer coefficient, and total heat transfer. Based on these analyses, the shell and tube heat exchanger was purposed as the most efficient heat exchanger with the overall heat transfer coefficient of 5.06 W/m²K.

Abstract Methanol is an important industrial chemical, and its synthesis and purification units are among the most widely used processes in the field of energy. The two-column separation unit of methanol has been analyzed from the thermodynamic and energy points of view in the present study. The simulation has been done by Aspen Hysys V11 and the SRK equation has been regarded as the most appropriate equation of state (EOS) for this simulation with the mean relative error (MRE) of 2 %. Then, the design of the heat exchanger network (HEN) has been calculated using the Aspen Energy Analyzer V11. Both distillation towers have been analyzed using pinch technology. As a result, the amount of hot and cold utilities used has been LP=1.482×〖10〗^8, MP=1.57×〖10〗^4, and Air =1.423×〖10〗^8, respectively. Besides, the total heating and cooling target of the process has been 1.482×〖10〗^8 and 1.423×〖10〗^8, accordingly. Then, the 〖∆T〗_min (minimum allowable temperature difference between hot and cold currents) and its effect on the annual cost have been investigated. The optimum value 〖∆T〗_min is determined to have better-operating conditions and to meet the design of the HEN economically. Reducing 〖∆T〗_min increases operating costs and reduces energy costs.

Abstract The fully mixed continuous stirred tank reactor is an important type of industrial reactors mainly used to produce high volume products such as petrochemicals, detergents, sanitary products and products that are in demand in the market. Knowing the dynamic behavior of chemical reactors is of great importance in setting up, designing, controlling and stopping reactors. In this paper, the effect of non-dimensional numbers Damkohler and Stanton on the stability of a continuous stirred tank reactor in which a first-order exothermic reaction takes place is investigated. First, a mathematical model of the system's dynamic behavior was presented. Then, by simultaneous solving of the equations of mass and energy around the fixed point in MATLAB software, the effect of the mentioned numbers was investigated. The results show that the continuous stirred tank reactor shows different behaviors in different ranges of Damkohler and Stanton numbers. This reactor behaves unstable in small and large ranges of Damkohler and Stanton numbers due to the presence of mixed or positive and negative eigenvalues. The best range for Damkohler and Stanton numbers is close to 1, because in this range the reactor shows stable behavior due to having two negative eigenvalues. In this range, in addition to the stability, the conversion is also 100%. Finaly the ratio of Stanton to DamKohler was investigated as St / Da˃1 and St / Da = 1. If St / Da = 1, the system is in steady state, but in St / Da˃1, the system moves away from steady state.

Abstract One of the effective catalysts for hydrogen purification and production via medium temperature shift reaction, is Cu-Ce solid solution. Cu0.1Ce0,9O1.9 was produced using co-precipitation method and then was utilized as support for 5Cu/Ce0.9Cu0.1O1.9 catalyst which was synthesized employing wet impregnation method. X-ray diffraction (XRD) analysis showed that crystalline sizes of Ce0.9Cu0.1O1.9 and 5Cu/Cu0.1Ce0,9O1.9 were 9.22 and 18.33 nm, respectively. The Catalysts were evaluated in medium temperature shift reaction at 300-390 °C and at gas hourly space velocities (GHSV) of 12000 and 30000 h-1, in a fixed bed reactor. Due to higher concentration of Cu and synergic positive effects of both active metal and support, 5Cu/Cu0.1Ce0,9O1.9 catalyst showed better performance. It was also concluded that, because of low residence time at high levels of GHSV, increasing GHSV leads to decrease CO conversion. Then 5Cu/Cu0.1Ce0,9O1.9 was evaluated in microchennel reactor in 2 GHSVs of 12000 and 30000 h-1 and results were compared with the fixed-bed reactor. It can be concluded that microchannel reactor is better in higher GHSVs (lower residence time of gas flow). A microchannel reactor provides a high surface-to-volume ratio and gases pass over the thin layer of catalyst on the coated plates. Hence, due to the better access to the catalytic bed, the reactants react even in a short time, which improves the microchannel performance compared to the fixed bed reactor