TY - JOUR ID - 11698 TI - Effect of graphite oxidation on the yield and quality of graphene synthesized by supercritical exfoliation and its application in photocatalytic degradation of methylene blue JO - Iranian Journal of Chemical Engineering(IJChE) JA - IJCHE LA - en SN - 1735-5397 AU - Hadi, A. AU - Karimi-Sabet, J. AU - Moosavian, S. M. A. AU - Ghorbanian, S. AD - Department of Chemical Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran AD - NFCRS, Nuclear Science and Technology Research Institute, Tehran, Iran AD - 1Department of Chemical Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran Y1 - 2015 PY - 2015 VL - 12 IS - 4 SP - 52 EP - 68 KW - graphene KW - Graphite KW - Supercritical Exfoliation KW - Graphite Oxide KW - Photocatalytic degradation DO - N2 - After fullerene and nanotubes, graphene is a new allotrope of carbon. This attractive nanomaterial can be produced by different methods. In this work, we have used the less common approach for preparation of graphene. This technique is based on the utilization of supercritical fluid. Ethanol was used as the solvent for exfoliation of pristine graphite, at the temperature of 400 oC and pressure of 40 MPa. In addition, supercritical ethanol was used to reduce and exfoliate graphite oxide. FT-IR spectra indicate that reduction and exfoliation of graphite oxide can be done in supercritical ethanol, simultaneously. Effect of graphite oxidation on the yield and quality of graphene was investigated and results showed that oxidation of graphite can improve the yield of supercritical process from 12.5% to 26.8%, but Raman spectra revealed that quality of graphene samples produced by graphite oxide is lower than neat graphite. Moreover, the impacts of initial graphite concentration and sonication power on the exfoliation yield were studied. Finally, hybrid structure of graphene and titanium dioxide nanoparticles were prepared by ultrasonic method and used for photocatalytic degradation of methylene blue dye pollutant. Results revealed that titanium dioxide nanoparticles show better photocatalytic performance in presence of graphene sheets. UR - https://www.ijche.com/article_11698.html L1 - https://www.ijche.com/article_11698_0a5022eb5c29b7daf432bd5031b00804.pdf ER -