Iranian Association of Chemical Engineering (IAChE) Iranian Journal of Chemical Engineering (IJChE) 1735-5397 18 3 2021 09 01 Optimization of the Adsorption of Pb(II) and Zn(II) onto the EDTA-Modified MnO2/Chitosan/Fe3O4 Nanocomposite from an Aqueous Solution Using RSM According to the CCD Method 33 51 143127 10.22034/ijche.2022.314204.1414 EN Adel Panahadeh Department of Chemical Engineering, Borujerd Branch, Islamic Azad University, Borujerd, Iran Arsalan Parvareh Razi University 0000-0002-0218-1162 Mostafa Moraveji Amirkabir university of technology (Tehran Polytechnic) 0000-0003-4891-340X Journal Article 2021 11 09 <em>The central composite design (CCD) was employed to investigate the adsorption of Pb(II) and Zn(II) metal ions as well as methylene blue (MB) as an aromatic anion by a new EDTA/MnO₂/CS/Fe₃O₄ synthesized nanocomposite. The effect of possible affective factors including the contaminant concentration (20-200 mg/L), pH (2-8), adsorbent content (0.1-0.9 g/L), and contact time (10-110 min) on the adsorption of the metal ions using response surface methodology (RSM) were studied. The highest removal percentages predicted by the model were 100.776 % and 87.069 %, respectively, for the removal of Pb(II) and Zn(II), that the value of more than 100 % in the case of Pb(II) was due to the model’s error. The effect of the simultaneous presence of methyl blue (MB) and the metal ions in the aqueous solution on the adsorption rate of each metal ion was investigated. The study of the adsorption isotherms in the single-component adsorption showed the dominance of Langmuir isotherm over the adsorption process of each pollutant (R² > 0.99). The maximum adsorption capacities according to the Langmuir model were 310.4 and 136 mg/g for lead and zinc ions, respectively, and 421.1 mg/g for methyl blue. The results showed that the studied nanocomposite still had high efficiency after five consecutive adsorption-desorption cycles</em> https://www.ijche.com/article_143127_147746d4cb74367588e8c310f6e35ff2.pdf