Document Type : Regular Article

Authors

Multiphase Systems Research Lab, School of Chemical Engineering, College of Engineering, University of Tehran, Iran

Abstract

The effect of adding isopropanol (ISP) to nitrogen as the fluidizing gas on the hydrodynamics of the fluidization of hydrophilic titanium nanoparticles was studied. It was shown by the pressure drop method that adding ISP reduces the minimum fluidization velocity. Wavelet transform of the pressure fluctuations of the bed was employed to identify the hydrodynamic structures. The energy of hydrodynamic structures was evaluated in each fluidization mode. It was shown that ISP reduces the inter-particle attractive forces by replacing the hydroxyl group of the hydrophilic nanoparticles with an alkyl group. Energy and recurrence analyses were used to define the characteristics of fluidization when adding ISP to nitrogen gas. The energy of macro structures increased when using ISP, having indicated a decrease in the number of bubbles and an increase in the bubble size due to the reduction of inter-particle attractive forces. The increase of the white local areas in the recurrence plots also showed the increase of the bubble size. The recurrence quantification analysis showed the increase of the larger-scale phenomena (i.e. bubbles) in the bed.

Keywords

Main Subjects

  • van Ommen, J. R., Valverde, J. M. and Pfeffer, R., “Fluidization of nanopowders: A review”, Journal of Nanoparticle Research, 14 (3), 1 (2012).
  • Yao, W., Guangsheng, G., Fei, W. and Jun, W., “Fluidization and agglomerate structure of SiO2 nanoparticles”, Powder Technology, 124 (1-2), 152 (2002).
  • Liu, Y., Ohara, H. and Tsutsumi, A., “Pulsation-assisted fluidized bed for the fluidization of easily agglomerated particles with wide size distributions”, Powder Technology, 316, 388 (2017).
  • Valverde, J. M. and Castellanos, A., “Effect of vibration on agglomerate particulate fluidization”, AIChE Journal, 52 (5), 1705 (2006).
  • An, K. and Andino, J. M., “Enhanced fluidization of nanosized TiO2 by a microjet and vibration assisted (MVA) method”, Powder Technology, 356, 200 (2019).
  • Hoorijani, H., Zarghami, R., Nosrati, K. and Mostoufi, N., “Investigating the hydrodynamics of vibro-fluidized bed of hydrophilic titanium nanoparticles”, Chemical Engineering Research and Design, 174, 486 (2021).
  • Zhao, Z., Liu, D., Ma, J. and Chen, X., “Fluidization of nanoparticle agglomerates assisted by combining vibration and stirring methods”, Chemical Engineering Journal, 388, 124213 (2020).
  • Tahmasebpoor, M., de Martín, L., Talebi, M., Mostoufi, N. and van Ommen, J. R., “The role of the hydrogen bond in dense nanoparticle–gas suspensions”, Physical Chemistry Chemical Physics, 15 (16), 5788 (2013).
  • Vahdat, M. T., Zarghami, R. and Mostoufi, N., “Fluidization characterization of nano-powders in the presence of electrical field”, The Canadian Journal of Chemical Engineering, 96 (5), 1109 (2018).
  • Liu, H. and Wang, S., “Fluidization behaviors of nanoparticle agglomerates with high initial bed heights”, Powder Technology, 388, 122 (2021).
  • Tamadondar, M. R., Zarghami, R., Tahmasebpoor, M. and Mostoufi, N., “Characterization of the bubbling fluidization of nanoparticles”, Particuology, 16, 75 (2014).
  • Esmailpour, A. A., Mostoufi, N. and Zarghami, R., “Effect of temperature on fluidization of hydrophilic and hydrophobic nanoparticle agglomerates”, Experimental Thermal and Fluid Science, 96, 63 (2018).
  • Karimi, F., Haghshenasfard, M., Sotudeh-Gharebagh, R., Zarghami, R. and Mostoufi, N., “Enhancing the fluidization quality of nanoparticles using external fields”, Advanced Powder Technology, 29 (12), 3145 (2018).
  • Tahmasebpoor, M., Zarghami, R., Sotudeh-Gharebagh, R. and Mostoufi, N., “Characterization of fluidized beds hydrodynamics by recurrence quantification analysis and wavelet transform”, International Journal of Multiphase Flow, 69, 31 (2015).
  • Rodrigues, A. P., D’Mello, G. and Srinivasa Pai, P., “Selection of mother wavelet for wavelet analysis of vibration signals in machining”, Journal of Mechanical Engineering and Automation, 6 (5A), 81 (2016).
  • Rioul, O. and Vetterli, M., “Wavelets and signal processing”, IEEE Signal Processing Magazine, 8 (4), 14 (1991).
  • Ziaei-Halimejani, H., Zarghami, R. and Mostoufi, N., “Investigation of hydrodynamics of gas-solid fluidized beds using cross recurrence quantification analysis”, Advanced Powder Technology, 28 (4), 1237 (2017).
  • Tahmasebpour, M., Zarghami, R., Sotudeh-Gharebagh, R. and Mostoufi, N., “Characterization of various structures in gas-solid fluidized beds by recurrence quantification analysis”, Particuology, 11 (6), 647 (2013).
  • Savari, C., Sotudeh‐Gharebagh, R., Zarghami, R. and Mostoufi, N., “Non‐intrusive characterization of particle size changes in fluidized beds using recurrence plots”, AIChE Journal, 62 (10), 3547 (2016).
  • Babaei, B., Zarghami, R. and Sotudeh‐Gharebagh, R., “Monitoring of fluidized beds hydrodynamics using recurrence quantification analysis”, AIChE Journal, 59 (2) 399 (2013).
  • van Ommen, J. R., Coppens, M. O., van den Bleek, C. M. and Schouten, J. C., “Early warning of agglomeration in fluidized beds by attractor comparison”, AIChE Journal, 46 (11), 2183 (2000).
  • Marwan, N., Romano, M. C., Thiel, M. and Kurths, J., “Recurrence plots for the analysis of complex systems”, Physics Reports, 438 (5-6), 237 (2007).
  • Eckmann, J. -P., Kamphorst, S. O. and Ruelle, D., “Recurrence plots of dynamical systems”, World Scientific Series on Nonlinear Science Series A, 16, 441 (1995).
  • Tahmasebpour, M., Zarghami, R., Sotudeh-Gharebagh, R. and Mostoufi, N., “Study of transition velocity from bubbling to turbulent fluidisation by recurrence plots analysis on pressure fluctuations”, The Canadian Journal of Chemical Engineering, 91 (2), 368 (2013).
  • Marwan, N., “A historical review of recurrence plots”, The European Physical Journal Special Topics, 164 (1), 3 (2008).
  • Webber Jr, C. L. and Zbilut, J. P., “Dynamical assessment of physiological systems and states using recurrence plot strategies”, Journal of Applied Physiology, 76 (2), 965 (1994).
  • Savari, C., Kulah, G., Sotudeh-Gharebagh, R., Mostoufi, N. and Koksal, M., “Early detection of agglomeration in conical spouted beds using recurrence plots”, Industrial & Engineering Chemistry Research, 55 (26), 7179 (2016).
  • Babaei, B., Zarghami, R., Sedighikamal, H., Sotudeh-Gharebagh, R. and Mostoufi, N., “Selection of minimal length of line in recurrence quantification analysis”, Physica A: Statistical Mechanics and its Applications, 395, 112 (2014).