Thermodynamics Research Laboratory, School of Chemical Engineering, Iran University of Science & Technology, Narmak, Tehran, Iran
Abstract
In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental surface tension data of single electrolyte solutions. Absolute average deviation was used as objective function in optimization procedure. The results showed that in the case of single electrolyte solutions different activity coefficient models have similar capability while in the case of mixed electrolyte solutions, extended UNIQUAC model gives better results.
Dadras,M. and Dehghani,M. (2013). Prediction of Surface Tension in Single and Mixed Electrolyte Solutions. Iranian Journal of Chemical Engineering (IJChE), 10(4), 3-15.
MLA
Dadras,M. , and Dehghani,M. . "Prediction of Surface Tension in Single and Mixed Electrolyte Solutions", Iranian Journal of Chemical Engineering (IJChE), 10, 4, 2013, 3-15.
HARVARD
Dadras M., Dehghani M. (2013). 'Prediction of Surface Tension in Single and Mixed Electrolyte Solutions', Iranian Journal of Chemical Engineering (IJChE), 10(4), pp. 3-15.
CHICAGO
M. Dadras and M. Dehghani, "Prediction of Surface Tension in Single and Mixed Electrolyte Solutions," Iranian Journal of Chemical Engineering (IJChE), 10 4 (2013): 3-15,
VANCOUVER
Dadras M., Dehghani M. Prediction of Surface Tension in Single and Mixed Electrolyte Solutions. IJChE, 2013; 10(4): 3-15.
