CFD Simulation and Enhancement of Liquid-Liquid Mass Transfer under the Effect of 1.7 MHz Ultrasonic Waves

Document Type : Regular Article

Authors

1 Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan, Iran

2 CFD Research Division, Advanced Chemical Engineering Research Center, Razi University, Kermanshah, Iran

Abstract
 This study investigates the two-phase flow simulation in a Y-type  micromixer with a circular pit at the junction with a 1.7 MHz ultrasonic (US) transducer. A CFD simulation is conducted on the micromixer under varying fluid flow rates. Initially, the simulation is performed without US waves, and subsequently, the US waves are applied. The influence of US waves on flow behavior, mass transfer coefficient (KLa), and extraction efficiency (E) is assessed and contrasts with the same in the scenario where no ultrasound is applied. The simulation outcomes exhibit strong agreement with the experimental findings of a reliable reference. The findings indicate that the flow pattern for both aqueous and organic phases is parallel within the micromixer when ultrasound is absent.   However, applying the US waves alters the flow pattern and enhances the mixing. Under the US field, the interface between the two phases is completely disrupted and the contact between them increases. It is concluded that applying US waves into the liquid medium enhances turbulence, mixing, and the mass transfer rate inside the micromixer.  The influence of the flow rate of the aqueous phase at different US powers on KLa and E was investigated. The decreasing trend of KLa is observed. The effect of the power of ultrasound (P=3.5, 5.25, and 7W) on KLa and E is investigated and results show that P= 7 W has the more ability to enhance the mass transfer rate. The maximum error that is obtained for KLa is 5.43 %, which shows the high accuracy of the CFD model.

Keywords

Subjects


[1]      Y. Yao, Y. Pan, and S. Liu, “Power ultrasound and its applications: A state-of-the-art review,” Ultrason. Sonochem., vol. 62, p. 104722, Apr. 2020, doi: 10.1016/j.ultsonch.2019.104722.
[2]      X. Zhu, R. S. Das, M. L. Bhavya, M. Garcia-Vaquero, and B. K. Tiwari, “Acoustic cavitation for agri-food applications: Mechanism of action, design of new systems, challenges and strategies for scale-up,” Ultrason. Sonochem., vol. 105, p. 106850, May 2024, doi: 10.1016/j.ultsonch.2024.106850.
[3]      N. J. Lakshmi, C. Agarkoti, P. R. Gogate, and A. B. Pandit, “Acoustic and hydrodynamic cavitation-based combined treatment techniques for the treatment of industrial real effluent containing mainly pharmaceutical compounds,” J. Environ. Chem. Eng., vol. 10, no. 5, p. 108349, Oct. 2022, doi: 10.1016/j.jece.2022.108349.
[4]      J. Stelmach, C. Kuncewicz, T. Jirout, and F. Rieger, “Mixing tank hydrodynamics and mixing efficiency for propeller impellers,” Chem. Eng. Res. Des., vol. 199, pp. 460–472, Nov. 2023, doi: 10.1016/j.cherd.2023.09.036.
[5]      M. Rahimi, N. Azimi, and F. Parvizian, “Using microparticles to enhance micromixing in a high frequency continuous flow sonoreactor,” Chem. Eng. Process. Process Intensif., vol. 70, 2013, doi: 10.1016/j.cep.2013.03.013.
[6]      F. Parvizian, M. Rahimi, and N. Azimi, “Macro- and micromixing studies on a high frequency continuous tubular sonoreactor,” Chem. Eng. Process. Process Intensif., vol. 57–58, pp. 8–15, Jul. 2012, doi: 10.1016/j.cep.2012.04.006.
[7]      S. Sochard, A.-M. Wilhelm, and H. Delmas, “Gas-vapour bubble dynamics and homogeneous sonochemistry,” Chem. Eng. Sci., vol. 53, no. 2, pp. 239–254, Jan. 1998, doi: 10.1016/S0009-2509(97)85744-2.
[8]      V. S. Moholkar, P. Senthil Kumar, and A. B. Pandit, “Hydrodynamic cavitation for sonochemical effects,” Ultrason. Sonochem., vol. 6, no. 1–2, pp. 53–65, Mar. 1999, doi: 10.1016/S1350-4177(98)00030-3.
[9]      M. Abolhasani, M. Rahimi, M. Dehbani, and A. A. Alsairafi, “CFD Modeling of Heat Transfer by 1.7 MHz Ultrasound Waves,” Numer. Heat Transf. Part A Appl., vol. 62, no. 10, pp. 822–841, Nov. 2012, doi: 10.1080/10407782.2012.712432.
[10]    B. Sajjadi, S. Asgharzadehahmadi, P. Asaithambi, A. A. A. Raman, and R. Parthasarathy, “Investigation of mass transfer intensification under power ultrasound irradiation using 3D computational simulation: A comparative analysis,” Ultrason. Sonochem., vol. 34, pp. 504–518, Jan. 2017, doi: 10.1016/j.ultsonch.2016.06.026.
[11]    M. Rahimi, N. Azimi, F. Parvizian, and A. A. A. A. Alsairafi, “Computational Fluid Dynamics modeling of micromixing performance in presence of microparticles in a tubular sonoreactor,” Comput. Chem. Eng., vol. 60, pp. 403–412, Jan. 2014, doi: 10.1016/j.compchemeng.2013.09.006.
[12]    M. Rahimi, O. Jafari, and A. Mohammdifar, “Intensification of liquid-liquid mass transfer in micromixer assisted by ultrasound irradiation and Fe3O4 nanoparticles,” Chem. Eng. Process. Process Intensif., vol. 111, pp. 79–88, Jan. 2017, doi: 10.1016/j.cep.2016.11.003.
[13]    N. Azimi, M. Rahimi, and P. Zangenehmehr, “Numerical Study of Mixing and Mass Transfer in a Micromixer by Stimulation of Magnetic Nanoparticles in a Magnetic Field,” Chem. Eng. Technol., vol. 44, no. 6, pp. 1084–1093, Jun. 2021, doi: 10.1002/ceat.202000030.
[14]    R. Ma, C. Fan, Y. Wang, J. Luo, J. Li, and Y. Ji, “Liquid-liquid microextraction in a rotating microchannel extractor,” Chem. Eng. Process. - Process Intensif., vol. 151, p. 107916, May 2020, doi: 10.1016/j.cep.2020.107916.
[15]    A. Vikhansky, “CFD modelling of turbulent liquid–liquid dispersion in a static mixer,” Chem. Eng. Process. - Process Intensif., vol. 149, p. 107840, Mar. 2020, doi: 10.1016/j.cep.2020.107840.
[16]    B.-G. Loh, S. Hyun, P. I. Ro, and C. Kleinstreuer, “Acoustic streaming induced by ultrasonic flexural vibrations and associated enhancement of convective heat transfer,” J. Acoust. Soc. Am., vol. 111, no. 2, pp. 875–883, Feb. 2002, doi: 10.1121/1.1433811.
[17]    P. J. Westervelt, “Parametric Acoustic Array,” J. Acoust. Soc. Am., vol. 35, no. 4, pp. 535–537, Apr. 1963, doi: 10.1121/1.1918525.
[18]    A. Weber, N. Herzog, and T. Bergmann, “Numerical simulations of gas–liquid flow in thermal sorption processes,” Comput. Chem. Eng., vol. 84, pp. 171–179, Jan. 2016, doi: 10.1016/j.compchemeng.2015.09.003.
[19]    Y. Zhao, G. Chen, and Q. Yuan, “Liquid–liquid two-phase mass transfer in the T-junction microchannels,” AIChE J., vol. 53, no. 12, pp. 3042–3053, Dec. 2007, doi: 10.1002/aic.11333.
[20]    Y. Su, Y. Zhao, G. Chen, and Q. Yuan, “Liquid–liquid two-phase flow and mass transfer characteristics in packed microchannels,” Chem. Eng. Sci., vol. 65, no. 13, pp. 3947–3956, Jul. 2010, doi: 10.1016/j.ces.2010.03.034.
[21]    A. R. Ahmadabadi, M. Rahimi, N. Azimi, and A. A. Alsairafi, “Natural convection heat transfer in an enclosure filled with fe3o4 ferrofluid under static magnetic field: experimental investigation and computational fluid dynamics modeling,” J. Enhanc. Heat Transf., vol. 29, no. 1, pp. 27–54, 2022, doi: 10.1615/JEnhHeatTransf.2021040051.