Investigating the Effect of Magnetic Field on the Thermal Conductivity of Ferrofluid Containing Fe3O4 and CoFe2O4 Spinel Ferrite Nanoparticles and Presenting a New Correlation

Document Type : Regular Article

Authors

Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan, Iran

Abstract
In this study, the effect of the presence of a magnetic field (MF) on the thermal conductivity of the nanofluid (NF) ( ) containing spinel ferrite nanoparticles (NPs) (MFe2O4, M=Fe, Co) was investigated. CoFe2O4 NPs were concentrated by the coprecipitation method. Both NPs were characterized by SEM, EDX, XRD, and VSM. The thermal conductivity was investigated and compared in the presence and absence of an MF. In addition to the intensity of MF (100, 200, 300, and 400 G), the effect of the concentration of NPs (from 0.25 to 2 Vol%) on  at a constant temperature of 25 °C was investigated. According to the results, in the absence of MF, the  of CoFe2O4/water ferrofluid (FF) was higher than that of Fe3O4/water FF in different concentrations. Furthermore, as the intensity of the MF increased, the  of both Fe3O4/water and CoFe2O4/water FFs increased. This increase was more observed for the FFs containing Fe3O4 NPs. At the highest concentration (2 Vol%), with the increase of MF up to 400 G, the  of Fe3O4/water has increased by about 3.2%, while this increase was about 1.8% for CoFe2O4/water. Increasing the volume percentage of NPs also had a positive effect on the thermal conductivity coefficient. Finally, according to the obtained results, correlations were presented to predict the  of both FFs according to the intensity of the MF and the concentration of NPs. The proposed correlations had a satisfactory accuracy with R2 values of 0.98 for both FFs.

Keywords

Subjects


[1]   B. M'hamed, N. A. C. Sidik, M. N. A. W. M. Yazid, R. Mamat, G. Najafi, and G. Kefayati, A review on why researchers apply external magnetic field on nanofluids, International Communications in Heat and Mass Transfer, 78 (2016) 60-67. https://doi.org/10.1016/j.icheatmasstransfer.2016.08.023
[2] B. Nilforooshan Dardashti, M. M. Shahmardan, and M. Nazari, Convection Heat transfer Fe3O4/Water in a Square microchannel Under Uniform Heat Flux and Magnetic Field, Amirkabir Journal of Mechanical Engineering, 53 (9) (2021) 4925-4942. https://doi.org/10.22060/mej.2021.18841.6901
[3] A. Jahanbakhshi, and A. Ahmadi Nadooshan, Effects of Magnetic Field on Natural Convection of Non-Newtonian Fluid in a Square Enclosure with a Central Heat Source, Amirkabir Journal of Mechanical Engineering, 53 (1) (2021) 259-278. https://doi.org/10.22060/mej.2019.16101.6274
[4] W. Rakpakdee , M. Motozawa , M. Fukuta , and W. Chaiworapuek, Characteristics of heat transfer and flow resistance of magnetic fluid flow through porous media combined with magnetic field effect, Experimental Thermal and Fluid Science, 144 (2023) 110851. https://doi.org/10.1016/j.expthermflusci.2023.110851.
[5]   M. Amani, P. Amani, A. Kasaeian, O. Mahian, and S. Wongwises, Thermal conductivity measurement of spinel-type ferrite MnFe2O4 nanofluids in the presence of a uniform magnetic field, Journal of Molecular Liquids, 230 (2017) 121-128. https://doi.org/10.1016/j.molliq.2016.12.013
[6]   N. Zheng, F. Yan, K. Zhang, T. Zhou, and Z. Sun, A review on single-phase convective heat transfer enhancement based on multi-longitudinal vortices in heat exchanger tubes, Applied Thermal Engineering, 164 (2020) 114475. https://doi.org/10.1016/j.applthermaleng.2019.114475
[7]   T. T. Baby, and S. Ramaprabhu, Magnetic nanoparticles decorated multiwalled carbon nanotubes dispersed nanofluids, in AIP Conference Proceedings, (2011) 965-966. https://doi.org/10.1063/1.3606180
[8]   P. Shima, and J. Philip, Tuning of thermal conductivity and rheology of nanofluids using an external stimulus, The Journal of Physical Chemistry C, 115 (2011) 20097-20104. https://doi.org/10.1021/jp204827q
[9]   A. Gavili, F. Zabihi, T. D. Isfahani, and J. Sabbaghzadeh, The thermal conductivity of water base ferrofluids under magnetic field, Experimental Thermal and Fluid Science, 41 (2012) 94-98. https://doi.org/10.1016/j.expthermflusci.2012.03.016.
[10] I. Nkurikiyimfura, Y. Wang, and Z. Pan, Effect of chain-like magnetite nanoparticle aggregates on thermal conductivity of magnetic nanofluid in magnetic field, Experimental Thermal and Fluid Science, 44 (2013) 607-612. https://doi.org/10.1016/j.expthermflusci.2012.08.024.
[11] M. Krichler, and S. Odenbach, Thermal conductivity measurements on ferrofluids with special reference to measuring arrangement, Journal of Magnetism and Magnetic Materials, 326 (2013) 85-90. https://doi.org/10.1016/j.jmmm.2012.08.037.
[12] A. Shahsavar, M. R. Salimpour, M. Saghafian,  and M. Shafii, Effect of magnetic field on thermal conductivity and viscosity of a magnetic nanofluid loaded with carbon nanotubes, Journal of Mechanical Science and Technology, 30 (2016) 809-815. https://doi.org/10.1007/s12206-016-0135-4
[13] I. Nurdin, I. I. Yaacob, and M. R. Johan, Enhancement of thermal conductivity and kinematic viscosity in magnetically controllable maghemite (γ-Fe2O3) nanofluids, Experimental Thermal and Fluid Science, 77 (2016) 265-271. https://doi.org/10.1016/j.expthermflusci.2016.05.002.
[14] M. Dinarvand, M. Abolhasani, F. Hormozi, and Z. Bahrami, Cooling capacity of magnetic nanofluid in presence of magnetic field based on first and second laws of thermodynamics analysis, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44 (3) (2022) 7825-7840. https://doi.org/10.1080/15567036.2021.1872746
[15] M. Dinarvand, M. Abolhasani, F. Hormozi, and Z. Bahrami, Effects of magnetic field gradient on heat transfer and irreversibility in a channel, Chemical Engineering Communications, 210 (5) (2023) 698-715. https://doi.org/10.1080/00986445.2021.1977927
[16] M. Dinarvand, M. Abolhasani, F. Hormozi, and Z. Bahrami, Experimental investigation and performance comparison of Fe3O4/water and CoFe2O4/water ferrofluids in presence of a magnetic field in a cooling system, Journal of the Taiwan Institute of Chemical Engineers, 148 (2023) 104927. https://doi.org/10.1016/j.jtice.2023.104927
[17] M. Dinarvand, M. Abolhasani, F. Hormozi, and Zohreh Bahrami, The effect of magnet distance from the channel containing ferrofluid on magnetic field intensity, Kelvin force and heat transfer, proceedings of the 10th National Conference on CFD Application in Chemical and Petroleum Industries, Kermanshah, Iran, (2022) 1-6. (In Persian)
[18]  M. Dinarvand, M. Abolhasani, and F. Hormozi, Effect of Magnetic Field Intensity on Hydrodynamic Entrance Length and Nusselt number,  The 11th International Chemical Engineering Congress & Exhibition (IChEC 2020) Fouman, Iran, (2020).
[19] M. Dinarvand, M. Abolhasani, F. Hormozi, Z. Bahrami, Investigation of the effect of nanoparticle type on ferrofluid viscosity and its thermal performance in the presence and absence of a magnetic field: A new correlation, Journal of Magnetism and Magnetic Materials, 587 (2023) 171270. https://doi.org/10.1016/j.jmmm.2023.171270.
[20] I. Sharifi, H. Shokrollahi, M. M. Doroodmand, and R. Safi, Magnetic and structural studies on CoFe2O4 nanoparticles synthesized by co-precipitation, normal micelles and reverse micelles methods, Journal of Magnetism and Magnetic Materials, 324 (2012) 1854-1861. https://doi.org/10.1016/j.jmmm.2012.01.015
[21] Y. I. Kim, D. Kim, and C. S. Lee, Synthesis and characterization of CoFe2O4 magnetic nanoparticles prepared by temperature-controlled coprecipitation method, Physica B: Condensed Matter, 337 (2003) 42-51. https://doi.org/10.1016/S0921-4526(03)00322-3
[22] W. Don, and H. Robert, Perry’s chemical engineers’ handbook, ed: McGraw-Hill Education, NY, (2008).
[23] Y.C. Sharma, V. Srivastava, C. Weng, S.N. Upadhyay, Removal of Cr(VI) from wastewater by adsorption on iron nanoparticles, The Canadian Journal of Chemical Engineering 87 (2009) 921-929. https://doi.org/10.1002/cjce.20230
[24] Shikha Dubey, Deepak Gusain, Yogesh C. Sharma, Kinetic and isotherm parameter determination for the removal of chromium from aqueous solutions by nanoalumina, a nanoadsorbent, Journal of Molecular Liquids 219 (2016) 1–8. https://doi.org/10.1016/j.molliq.2016.01.021