1
School of Chemical Engineering, Iran University of Science and Technology Tehran, Iran
2
Faculty of Chemical Engineering, Arak University, Arak, Iran
Abstract
In this work a simplified model based on perturbation theory is presented for prediction of activity coefficient of amino acids and electrolytes in aqueous electrolyte solution. In comparison with previous works, in this model a new hard sphere equation of state has been utilized as a reference term while other interactions such as charge-charge, charge-dipole, dipole-dipole and dipole-induced dipole have been considered as perturbation terms. For simplification, solvent has been considered as dielectric continuum. Finally, aqueous electrolyte solutions containing amino acids have been modeled just using two adjustable parameters. The results have been compared with similar models and it is shown that new hard spheres equation of state shows an improvement in accuracy of the model.
Salehi,E. , Dehghani,M. and Fazlali,A. (2013). A Simplified Perturbation Model for Prediction of Mean Ionic Activity Coefficient in Aqueous Electrolyte Solution. Iranian Journal of Chemical Engineering (IJChE), 10(3), 14-26.
MLA
Salehi,E. , , Dehghani,M. , and Fazlali,A. . "A Simplified Perturbation Model for Prediction of Mean Ionic Activity Coefficient in Aqueous Electrolyte Solution", Iranian Journal of Chemical Engineering (IJChE), 10, 3, 2013, 14-26.
HARVARD
Salehi E., Dehghani M., Fazlali A. (2013). 'A Simplified Perturbation Model for Prediction of Mean Ionic Activity Coefficient in Aqueous Electrolyte Solution', Iranian Journal of Chemical Engineering (IJChE), 10(3), pp. 14-26.
CHICAGO
E. Salehi, M. Dehghani and A. Fazlali, "A Simplified Perturbation Model for Prediction of Mean Ionic Activity Coefficient in Aqueous Electrolyte Solution," Iranian Journal of Chemical Engineering (IJChE), 10 3 (2013): 14-26,
VANCOUVER
Salehi E., Dehghani M., Fazlali A. A Simplified Perturbation Model for Prediction of Mean Ionic Activity Coefficient in Aqueous Electrolyte Solution. IJChE, 2013; 10(3): 14-26.
