Mathematical Modeling of Mass Transfer during Solid-Liquid Extraction in Fixed, Expanded and Fluidized-Bed Columns

Document Type : Regular Article

Authors

Chemical Engineering Department, Faculty of Engineering, University of Guilan, Rasht, Iran

Abstract
In this paper, modeling approaches were given for explaining mass transfer during solid-liquid extraction in continuous fixed, expanded, and fluidized-bed extractors. The first approach utilizes a differential mass balance-based model, focusing on the differential mass conservation within an element of fixed and expanded-bed columns. The second approach employs a model by applying a mass balance concept to a control volume of the fluidized-bed column. The differential mass balance method segments the column into well-mixed stages, with the fluid flowing axially in an ideal plug flow regime. The solute diffusion inside the porous particles is modeled using Fick's second law of diffusion. Modeling parameters like the effective diffusivity and equilibrium concentration were estimated using the batch extraction experiments. These models were developed and validated using experimental column data involving the extraction of potassium bicarbonate from polyamide 6 pellets with distilled water as the solvent. The modeling results show a good agreement with experimental data.

Keywords

Subjects


  1. Zhang, Q.-W., L.-G. Lin, and W.-C. Ye, Techniques for extraction and isolation of natural products: A comprehensive review. Chinese medicine, 2018. 13: p. 1-26. https://doi.org/10.1186/s13020-018-0177-x
  2. Gallo, M., et al., A water extraction process for lycopene from tomato waste using a pressurized method: An application of a numerical simulation. European Food Research and Technology, 2019. 245: p. 1767-1775. https://doi.org/10.1007/s00217-019-03300-5.
  3. Kakumanu, V.K. and A.K. Bansal, Supercritical fluid technology in pharmaceutical research. Crips, 2003. 4(83): p. 8-12.
  4. Mohamed, R.S. and G.A. Mansoori, The use of supercritical fluid extraction technology in food processing. Food Technology Magazine, 2002. 20(7): p. 134-139.
  5. Naik, S., H. Lentz, and R. Maheshwari, Extraction of perfumes and flavours from plant materials with liquid carbon dioxide under liquid—vapor equilibrium conditions. Fluid Phase Equilibria, 1989. 49: p. 115-126. https://doi.org/10.1016/0378-3812(89)80009-3
  6. Naviglio, D., et al., Rapid Solid-Liquid Dynamic Extraction (RSLDE): A powerful and greener alternative to the latest solid-liquid extraction techniques. Foods, 2019. 8(7): p. 245. https://doi.org/3390/foods8070245
  7. Rasul, M.G., Conventional extraction methods use in medicinal plants, their advantages and disadvantages. Int. J. Basic Sci. Appl. Comput, 2018. 2: p. 10-14.
  8. Cvetanović, A., Extractions without organic solvents: advantages and disadvantages. Chemistry Africa, 2019. 2(3): p. 343-349. https://doi.org/10.1007/s42250-019-00070-1.
  9. Lopez, N., et al., Enhancement of the solid-liquid extraction of sucrose from sugar beet (Beta vulgaris) by pulsed electric fields. LWT-Food Science and Technology, 2009. 42(10): p. 1674-1680. https://doi.org/10.1016/j.lwt.2009.05.015.
  10. Pin, K., et al., Solid‐liquid extraction of betel leaves (piper Betle L.). Journal of Food Process Engineering, 2011. 34(3): p. 549-565. https://doi.org/10.1111/j.1745-4530.2009.00395.x
  11. Das, I. and A. Arora, Kinetics and mechanistic models of solid-liquid extraction of pectin using advance green techniques-a review. Food Hydrocolloids, 2021. 120: p. 106931. https://doi.org/10.1016/j.foodhyd.2021.106931
  12. Kassing, M., et al., A new approach for process development of plant‐based extraction processes. Chemical Engineering & Technology: Industrial Chemistry‐Plant Equipment‐Process Engineering‐Biotechnology, 2010. 33(3): p. 377-387. https://doi.org/10.1002/ceat.200900480
  13. Liu, J., et al., Pressurised hot water extraction in continuous flow mode for thermolabile compounds: extraction of polyphenols in red onions. Analytical and Bioanalytical Chemistry, 2014. 406: p. 441-445. https://doi.org/10.1007/s00216-013-7370-7
  14. Mosca, F., et al., Continuous or batch solid-liquid extraction of antioxidant compounds from seeds of Sterculia apetala plant and kinetic release study. Molecules, 2018. 23(7): p. 1759. https://doi.org/3390/molecules23071759
  15. Pinelo, M., J. Sineiro, and M.a.J. Núñez, Mass transfer during continuous solid–liquid extraction of antioxidants from grape byproducts. Journal of Food Engineering, 2006. 77(1): p. 57-63. https://doi.org/10.1016/j.jfoodeng.2005.06.021.
  16. Poirot, R., et al., Fast batch to continuous solid‐liquid extraction from plants in continuous industrial extractor. Chemical Engineering & Technology: Industrial Chemistry‐Plant Equipment‐Process Engineering‐Biotechnology, 2007. 30(1): p. 46-51. https://doi.org/10.1002/ceat.200600304
  17. Simeonov, E. and C. Chilev, Modelling and kinetics study of solid-liquid extraction from leaves of Nicotiana tabacum L. Journal of Chemical Technology and Metallurgy, 2015. 50(5): p. 597-600.
  18. Singh, S., S.K. Sharma, and S.K. Kansal, Dataset on aqueous solid-liquid extraction of gossypol from defatted cottonseed in acidic medium using green solvent, its kinetics and thermodynamics study and mass transfer effects. Data in Brief, 2020. 31: p. 105620. https://doi.org/10.1016/j.dib.2020.105620.
  19. Aichour, A., et al., Low-cost, biodegradable and highly effective adsorbents for batch and column fixed bed adsorption processes of methylene blue. Journal of Environmental Chemical Engineering, 2019. 7(5): p. 103409. https://doi.org/10.1016/j.jece.2019.103409.
  20. Crini, G., et al., Adsorption-oriented processes using conventional and non-conventional adsorbents for wastewater treatment. Green adsorbents for pollutant removal: fundamentals and design, 2018: p. 23-71. https://doi.org/10.1007/978-3-319-92111-2_2.
  21. Tovar-Gómez, R., et al., Modeling of fixed-bed adsorption of fluoride on bone char using a hybrid neural network approach. Chemical Engineering Journal, 2013. 228: p. 1098-1109. https://doi.org/10.1016/j.cej.2013.05.080
  22. Du, Z., et al., Modelling and development of a modular oscillating-bed adsorption reactor system for copper ion removal from water in emergency. Separation and Purification Technology, 2020. 233: p. 115933. https://doi.org/10.1016/j.seppur.2019.115933
  23. Horio, M., Fluidization science, its development and future. Particuology, 2010. 8(6): p. 514-524. https://doi.org/10.1016/j.partic.2010.08.010
  24. Park, Y.-G., et al., Mass transfer in semi-fluidized and fluidized ion-exchange beds. Environmental Engineering Research, 1999. 4(2): p. 71-71.
  25. Patel, H., Fixed-bed column adsorption study: a comprehensive review. Applied Water Science, 2019. 9(3): p. 45. https://doi.org/10.1007/s13201-019-0927-7
  26. Pintor, A.M., et al., Oil and grease removal from wastewaters: sorption treatment as an alternative to state-of-the-art technologies. A critical review. Chemical Engineering Journal, 2016. 297: p. 229-255. https://doi.org/10.1016/j.cej.2016.03.121
  27. Sulaymon, A.H., A. Mohammed, and T. Al-Musawi, Column biosorption of lead, cadmium, copper, and arsenic ions onto algae. J Bioproces Biotechniq, 2013. 3(1): p. 1-7. https://doi.org/0.4172/2155-9821.1000128
  28. Escudie, R., et al., Effect of particle shape on liquid-fluidized beds of binary (and ternary) solids mixtures: segregation vs. mixing. Chemical Engineering Science, 2006. 61(5): p. 1528-1539. https://doi.org/10.1016/j.ces.2005.08.028.
  29. McKay, G., Fluidized bed adsorption of pollutants on to activated carbon. The Chemical Engineering Journal, 1988. 39(2): p. 87-96. https://doi.org/10.1016/0300-9467(88)80099-6.
  30. Bardy, D., et al., An experimental investigation of fixed and fluidized beds as adsorbers in compact thermal energy storage systems. Journal of Energy Storage, 2020. 31: p. 101648. https://doi.org/10.1016/j.est.2020.101648.
  31. Chase, H.A., Purification of proteins by adsorption chromatography in expanded beds. Trends in Biotechnology, 1994. 12(8): p. 296-303. https://doi.org/10.1016/0167-7799(94)90046-9
  32. Koppejan, V., et al., Mathematical modelling of expanded bed adsorption–a perspective on in silico process design. Journal of Chemical Technology & Biotechnology, 2018. 93(7): p. 1815-1826. https://doi.org/1002/jctb.5595
  33. Reichert, U., et al., Isolation of a recombinant formate dehydrogenase by pseudo-affinity expanded bed adsorption. Journal of Biochemical and Biophysical Methods, 2001. 49(1-3): p. 533-552. https://doi.org/10.1016/S0165-022X(01)00218-4
  34. Thombare, M.A., et al., Solid-liquid circulating fluidized bed: a way forward. Reviews in Chemical Engineering, 2018. 35(1): p. 1-44. https://doi.org/1515/revce-2017-0017
  35. Pata, J. and M. Hartman, Minimum fluidization velocities of lime and limestone particles. Industrial & Engineering Chemistry Process Design and Development, 1978. 17(3): p. 231-236. https://doi.org/10.1021/i260067a003
  36. Al‐Jabari, M., Kinetic models of supercritical fluid extraction. Journal of separation science, 2002. 25(8): p. 477-489.https://doi.org/10.1002/1615-9314(20020601)25:8<477::AID-JSSC477>3.0.CO;2-C
  37. May Lin, T., et al., Mass transfer coefficients and correlation of supercritical carbon dioxide extraction of Sarawak black pepper. International Journal of Food Engineering, 2013. 10(1): p. 1-15. https://doi.org/10.1515/ijfe-2012-0219
  38. Rakotondramasy-Rabesiaka, L., et al., Solid–liquid extraction of protopine from Fumaria officinalis L.—analysis determination, kinetic reaction and model building. Separation and Purification Technology, 2007. 54(2): p. 253-261. https://doi.org/10.1016/j.seppur.2006.09.015
  39. Gertenbach, D., Solid-liquid extraction technologies for manufacturing nutraceuticals. Functional foods: biochemical and processing aspects, 2002. 2: p. 331-366.
  40. Karacabey, E. and G. Mazza, Optimization of solid− liquid extraction of resveratrol and other phenolic compounds from milled grape canes (Vitis vinifera). Journal of agricultural and food chemistry, 2008. 56(15): p. 6318-6325. https://doi.org/10.1021/jf800687b
  41. Durán, R., et al., Pectin extraction from mango peels in batch reactor: dynamic one-dimensional modeling and lattice Boltzmann simulation. Chemical Product and Process Modeling, 2015. 10(3): p. 203-210. https://doi.org/1515/cppm-2015-0014
  42. El‐Belghiti, K., Z. Rabhi, and E. Vorobiev, Kinetic model of sugar diffusion from sugar beet tissue treated by pulsed electric field. Journal of the Science of Food and Agriculture, 2005. 85(2): p. 213-218. https://doi.org/10.1002/jsfa.1944
  43. Ghoreishi, S. and R.G. Shahrestani, Subcritical water extraction of mannitol from olive leaves. Journal of Food Engineering, 2009. 93(4): p. 474-481. https://doi.org/10.1016/j.jfoodeng.2009.02.015
  44. Goodarznia, I. and M.H. Eikani, Supercritical carbon dioxide extraction of essential oils: Modeling and simulation. Chemical Engineering Science, 1998. 53(7): p. 1387-1395. https://doi.org/10.1016/S0009-2509(97)90445-0
  45. Goto, M., M. Sato, and T. Hirose, Extraction of peppermint oil by supercritical carbon dioxide. Journal of Chemical Engineering of Japan, 1993. 26(4): p. 401-407. https://doi.org/10.1252/jcej.26.401
  46. Honarvar, B., et al., Mathematical modeling of supercritical fluid extraction of oil from canola and sesame seeds. Brazilian Journal of Chemical Engineering, 2013. 30: p. 159-166. https://doi.org/1590/S0104-66322013000100018
  47. Qu, W., Z. Pan, and H. Ma, Extraction modeling and activities of antioxidants from pomegranate marc. Journal of food engineering, 2010. 99(1): p. 16-23. https://doi.org/10.1016/j.jfoodeng.2010.01.020
  48. Reverchon, E., Mathematical modeling of supercritical extraction of sage oil. AIChE Journal, 1996. 42(6): p. 1765-1771. https://doi.org/10.1002/aic.690420627
  49. Srinivasan, M., J. Smith, and B. McCoy, Supercritical fluid desorption from activated carbon. Chemical Engineering Science, 1990. 45(7): p. 1885-1895. https://doi.org/10.1016/0009-2509(90)87064-Y
  50. Wang, Y., V. Herdegen, and J.-U. Repke, Identification and analysis of mass transfer coefficients and effective diffusion coefficients for models of solvent extraction of Montan wax. Separation Science and Technology, 2016. 51(13): p. 2183-2197. https://doi.org/10.1080/01496395.2016.1202978
  51. Xavier, V.B., et al., Mathematical modeling for extraction of essential oil from Baccharis spp. by steam distillation. Industrial Crops and Products, 2011. 33(3): p. 599-604.
  52. Ziaedini, A., A. Jafari, and A. Zakeri, Extraction of antioxidants and caffeine from green tea (Camelia sinensis) leaves: kinetics and modeling. Food Science and Technology International, 2010. 16(6): p. 505-510. https://doi.org/1177/1082013210367567
  53. Spiro, M., M. Kandiah, and W. Price, Extraction of ginger rhizome: kinetic studies with dichloromethane, ethanol, 2‐propanol and an acetone—water mixture. International journal of food science & technology, 1990. 25(2): p. 157-167. https://doi.org/10.1111/j.1365-2621.1990.tb01070.x
  54. Crank, J., The mathematics of diffusion. 1979: Oxford university press.
  55. Perez, E.E., A.A. Carelli, and G.H. Crapiste, Temperature-dependent diffusion coefficient of oil from different sunflower seeds during extraction with hexane. Journal of Food Engineering, 2011. 105(1): p. 180-185. https://doi.org/10.1016/j.jfoodeng.2011.02.025
  56. Levenspiel, O., Chemical reaction engineering. 1998: John wiley & sons.
  57. Marković, A., A.-S. Morgenstern, and M. Petkovska, Evaluation of the potential of periodically operated reactors based on the second order frequency response function. Chemical Engineering Research and Design, 2008. 86(7): p. 682-691. https://doi.org/10.1016/j.cherd.2008.02.003.
  58. Deitmann, E., et al., Impact of residence time distributions in reacting magnesium packed-beds on Grignard reagent formation–Pump-induced flow behaviour in non-reacting magnesium beds (part 1). 2023. https://doi.org/10.1039/D3RE00190C
  59. Kelley, R. and F. Billmeyer, Evaluating dispersion in gel permeation chromatography. Axial dispersion of polymer molecules in packed beds of nonporous glass beads. Analytical Chemistry, 1969. 41(7): p. 874-879. https://doi.org/10.1016/0021-9673(68)80062-7
  60. Kolev, S.D. and E. Pungor, Description of an axially-dispersed plug flow model for the flow pattern in elements of fluid systems. Analytica chimica acta, 1986. 185: p. 315-319. https://doi.org/10.1016/0003-2670(86)80059-9
  61. Pietsch, S., et al., Measurement of residence time distributions in a continuously operated spouted bed. Chemical Engineering & Technology, 2020. 43(5): p. 804-812. https://doi.org/10.1002/ceat.201900453
  62. Shomali, A. and B. Abbasi Souraki, Experimental investigation and mathematical modeling of drying of green tea leaves in a multi-tray cabinet dryer. Heat and Mass Transfer, 2019. 55: p. 3645-3659. https://doi.org/1007/s00231-019-02662-6
  63. Villermaux, J., Chemical engineering approach to dynamic modelling of linear chromatography: A flexible method for representing complex phenomena from simple concepts. Journal of Chromatography A, 1987. 406: p. 11-26. https://doi.org/10.1016/S0021-9673(00)94014-7
  64. Menoud, P., L. Cavin, and A. Renken, Modelling of heavy metals adsorption to a chelating resin in a fluidized bed reactor. Chemical Engineering and Processing: Process Intensification, 1998. 37(1): p. 89-101. https://doi.org/10.1016/S0255-2701(97)00042-1
  65. Ayala-Aponte, A.A., A. Molina-Cortés, and L. Serna-Cock, Osmotic dehydration of green mango samples (Mangifera indica L., Filipino Var.) in ternary solutions. Vitae, 2018. 25(1): p. 8-16. https://doi.org/17533/udea.vitae.v25n1a02
  66. Anspach, F.B., et al., Expanded-bed chromatography in primary protein purification. Journal of Chromatography A, 1999. 865(1-2): p. 129-144. https://doi.org/1016/s0021-9673(99)01119-x
  67. Ergun, S., Fluid flow through packed columns. Chemical engineering progress, 1952. 48(2): p. 89.
  68. Kunii, D. and O. Levenspiel, Fluidization engineering. 1991: Butterworth-Heinemann.
  69. Wen, C. and Y. Yu, A generalized method for predicting the minimum fluidization velocity. AIChE journal, 1966. 12(3): p. 610-612.
  70. Wang, L., et al., Hierarchical porous polyamide 6 by solution foaming: synthesis, characterization and properties. Polymers, 2018. 10(12): p. 1310. https://doi.org/10.3390/polym10121310